Reputable factory supply Diphenylsilane 775-12-2 in bulk at low price

Q: What is the Diphenylsilane?

Diphenylsilane is clear colorless liquid, while it's Molecular Formula is C12H12Si. clear colorless liquid Thiocarbonyl derivatives of secondary alcohols are readily reduced by diphenylsilane in a radical chain process at room temperature using triethylborane-air as an initiator. An improved radical chain procedure for the deoxygenation of secondary and primary alcohols using diphenylsilane as hydrogen atom donor and triethylborane-air as initiator. Diphenylsilane is a reagent in the invention of radical reactions for deoxygenation of alcohols via their thiocarbonyl derivatives, deamination via isonitriles, and dehalogenation of bromo- and iodo- compounds by radical chain chemistry. Fluorescent film sensor for vapor-phase nitroaromatic explosives via monolayer assembly of oligo(diphenylsilane) on glass plate surfaces. Reductions of carboxylic acid derivatives by silanes in the presence of rhodium complexes were studied. Carboxylic esters were reduced to alcohols by diphenylsilane catalyzed by [RhCl (cod)] 2/4PPh 3 or [RhCl (PPh 3) 3] at room temperature in up to 99% yields. Sequential C- Si bond formations from diphenylsilane and its application to silanediol peptide isostere precursors.

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Diphenylsilane

Product Name Diphenylsilane
cas 775-12-2
purity 99%

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1.What is the Diphenylsilane ?

clear colorless liquid

2.What is the CAS number for Diphenylsilane ?

The CAS number of Diphenylsilane is 775-12-2.

3.What are another words for Diphenylsilane ?

Synonyms?for?Diphenylsilane 775-12-2:Silane,diphenyl- (6CI,8CI,9CI);Diphenylsilane;NSC 33013;SID 4559.0;TSL 8224;

4.What is Diphenylsilane (775-12-2) used for?

Thiocarbonyl derivatives of secondary alcohols are readily reduced by diphenylsilane in a radical chain process at room temperature using triethylborane-air as an initiator. An improved radical chain procedure for the deoxygenation of secondary and primary alcohols using diphenylsilane as hydrogen atom donor and triethylborane-air as initiator. Diphenylsilane is a reagent in the invention of radical reactions for deoxygenation of alcohols via their thiocarbonyl derivatives, deamination via isonitriles, and dehalogenation of bromo- and iodo- compounds by radical chain chemistry. Fluorescent film sensor for vapor-phase nitroaromatic explosives via monolayer assembly of oligo(diphenylsilane) on glass plate surfaces. Reductions of carboxylic acid derivatives by silanes in the presence of rhodium complexes were studied. Carboxylic esters were reduced to alcohols by diphenylsilane catalyzed by [RhCl (cod)] 2/4PPh 3 or [RhCl (PPh 3) 3] at room temperature in up to 99% yields. Sequential C- Si bond formations from diphenylsilane and its application to silanediol peptide isostere precursors.

InChI:InChI=1/C12H12Si/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10H,13H2

Relevant articles related to Diphenylsilane:

Article	Source
Interconversion of silylphenyl and phenylsilyl cations in the reaction with benzene	Shishigin,Avrorin,Kochina,Sinotova,Ignat'ev , p. 1393 - 1394 (2005)
Palladium(II) catalysed silicon-oxygen bond formation versus rearrangement reactions	Purkayastha,Baruah , p. 9 - 14 (2001)
Nickel-catalyzed cyclopolymerization of hexyl- and phenylsilanes	Tanabe, Makoto,Takahashi, Atsushi,Fukuta, Tomoko,Osakada, Kohtaro , p. 1037 - 1043 (2013)

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